- Clark, V.H.J., Owens, A., Tennyson, J., Yurchenko, S.N., "The high-temperature rotation-vibration spectrum and rotational clustering of silylene (SiH2)", Journal of Quantitative Spectroscopy and Radiative Transfer In press (2020).
- Wu, Y., Zhang, C., Ma, H., "Ab initio conical intersections for the Si (1D) + H2 reaction system: A lowest five singlet states study", RSC Advances 7, 12074-12084 (2017). [link to article][17WuZhCh.SiH2]
- Kokkin, D. L., Ma, T., Steimle, T., Sears, T. J., "Detection and characterization of singly deuterated silylene, SiHD, via optical spectroscopy", Journal of Chemical Physics 144, 244304 (2016). [link to article][16KoMaSt.SiH2]
- Zaari, R. R., Varganov, S. A., "Nonadiabatic transition state theory and trajectory surface hopping dynamics: Intersystem crossing between 3B1 and 1A1 states of SiH2", Journal of Physical Chemistry A 119, 1332-1338 (2015). [link to article][15ZaVaxx.SiH2]
- Shi, D.-H., Zhang, J.-P., Sun, J.-F., Liu, Y.-F., Zhu, Z.-L., "Analytic potential energy function of the SiH2 (C2v, X 1A1) radical using CCSD(T) theory in combination with quintuple correlation-consistent basis set", Acta Physica Sinica 58, 5329-5334 (2009). [link to article][09ShZhSu.SiH2]
- Jiang, L.-J., Lu, Y.-F., Lu, Z.-Z., Han, X.-Q., "The structure and potential energy function investigation on SiX2 (X = H, F) molecules", Acta Physica Sinica 58, 201-208 (2009). [link to article][09JiLuZh.SiH2]
- Feng, X., Zhu, Z.-H., Liu, X.-Y., Yang, X.-D., Huang, W., "Theoretical study on molecular reaction dynamics of the SiH2 system", Acta Physica Sinica 58, 8217-8223 (2009). [link to article][09XiZhXi.SH2]
- Tokue, I., Yamasaki, K., Nanbu, S., "Isotope effects in the dissociation of the B̃ 1A1 state of SiH2, SiHD and SiD2 using three-dimensional wave packet propagation", Journal of Chemical Physics 124, 114308 (2006). [link to article][06ToYaNa.SiH2]
- Guerout, R., Bunker, P. R., Jensen, P., Kraemer, W. P., "A calculation of the rovibronic energies and spectrum of the B̃ 1A1 electronic state of SiH2", Journal of Chemical Physics 123, 244312 (2005). [link to article][05GuBuJe.SiH2]
- Muramoto, Y., Ishikawa, H., Mikami, N., "First observation of the B̃ 1A1 state of SiH2 and SiD2 radicals by optical-optical double resonance spectroscopy", Journal of Chemical Physics 122, 154302 (2005). [link to article][05MuIsMi.SiH2]
- Tokue, I., Yamasaki, K., Nanbu, S., "Vibrational energies for the X̃ 1A1, Ã 1B1, and B̃ 1A1 states of SiH2 ∕ SiD2 and related transition probabilities based on global potential energy surfaces", Journal of Chemical Physics 122, 144307 (2005). [link to article][05ToYaNa.SiH2]
- Yurchenko, S. N., Bunker, P. R., Kraemer, W. P., Jensen, P., "The spectrum of singlet SiH2", Canadian Journal of Chemistry 82, 694-708 (2004). [link to article][04YuBuKr.SiH2]
- Hirata, S., Yanai, T., de Jong, W. A., Nakajima, T., Hirao, K., "Third-order Douglas-Kroll relativistic coupled-cluster theory through connected single, double, triple, and quadruple substitutions: Applications to diatomic and triatomic hydrides", Journal of Chemical Physics 120, 3297-3310 (2004). [link to article][04HiYaJo.SiH2]
- Kalemos, A., Dunning, T. H., Mavridis, A., "SiH2: A critical study", Molecular Physics 102, 2597-2606 (2004). [link to article][04KaDuMa.SiH2]
- Apeloig, Y., Pauncz, R., Karni, M., West, R., Steiner, W., Chapman, D., "Why is methylene a ground state triplet while silylene is a ground state singlet?", Organometallics 22, 3250-3256 (2003). [link to article][03ApPaKa.SiH2]
- Nakajima, M., Kawai, A., Fukushima, M., Obi, K., "LIF spectroscopy and dissociation dynamics of the SiH2 radical in the A 1B1 (1, v2, 0) state", Chemical Physics Letters 364, 99-107 (2002). [link to article][02MNaKaFu.SiH2]
- Ishikawa, H., Muramoto, Y., Mikami, N., "Stimulated emission pumping spectroscopy of SiH2: First observation of the spin–orbit interaction between the X̃ 1A1 and the ã 3B1 states", Journal of Molecular Spectroscopy 216, 90-97 (2002). [link to article][02IsMuMi.SiH2]
- Gaspar, P. P., Xiao, M. C., Pae, D. H., Berger, D. J., Haile, T., Chen, T. Q., Lei, D. Q., Winchester, W. R., Jiang, P., "The quest for triplet ground state silylenes", Journal of Organometallic Chemistry 646, 68-79 (2002). [link to article][02GaXiPa.SiH2]
- Makowe, J., Boyarkin, O. V., Rizzo, T. R., "Collision-free infrared multiphoton dissociation of silane", Journal of Physical Chemistry A 104, 11505-11511 (2000). [link to article][00MaBoRi.SiH2]
- Pak, C., Rienstra-Kiracofe, J. C., Schaefer, H. F., "Electron affinities of silicon hydrides: SiHn (n = 0-4) and Si2Hn (n = 0-6)", Journal of Physical Chemistry A 104, 11232-11242 (2000). [link to article][00PaRiSc.SiH2]
- Hirota, E., Ishikawa, H., "The vibrational spectrum and molecular constants of silicon dihydride SiH2 in the ground electronic state", Journal of Chemical Physics 110, 4254-4257 (1999). [link to article][99HiIsxx.SiH2]
- Pittner, J., Nachtigall, P., Carsky, P., Masik, J., Hubac, I., "Assessment of the single-root multireference Brillouin–Wigner coupled- cluster method: Test calculations on CH2, SiH2 and twisted ethylene", Journal of Chemical Physics 110, 10275-10282 (1999). [link to article][99PiNaCa.SiH2]
- Escribano, R., Campargue, A., "Absorption spectroscopy of SiH2 near 640 nm", Journal of Chemical Physics 108, 6249-6257 (1998). [link to article][98EsCaxx.SiH2]
- Havlas, Z., Downing, J. W., Michl, J., "Spin-orbit coupling in biradicals. 2. Ab initio methodology and
application to 1,1-biradicals: Carbene and silylene", Journal of Physical Chemistry A 102, 5681-5692 (1998). [link to article][98HaDoMi.SiH2]
- Campargue, A., Romanini, D., Sadeghi, N., "Measurement of SiH2 density in a discharge by intracavity laser
absorption spectroscopy and CW cavity ring-down spectroscopy", Journal of Physics D: Applied Physics 31, 1168-1175 (1998). [link to article][98CaRoSa.SiH2]
- Gupte, G. R., Prasad, R., "Ground state geometries and vibrational spectra of small hydrogenated
silicon clusters using nonorthogonal tight-binding molecular dynamics", International Journal of Modern Physics B 12, 1607-1622 (1998). [link to article][98GuPrxx.SiH2]
- Zaitsevskii, A., Malrieu, J. P., "Spin-adapted multipartitioning perturbation theory", Theoretical Chemistry Accounts 96, 269-276 (1997). [link to article][97ZaMaxx.ScH]
- Yamaguchi, Y., Van Huis, T. J., Sherrill, C. D., Schaefer, H. F., "The (X)over-tilde(1)A(1), (a)over-tilde(3)B(1), (A)over-tilde(1)B(1), and (B)over-tilde(1)A(1) electronic states of SiH2", Theoretical Chemistry Accounts 97, 341-349 (1997). [link to article][97YaVaSh.SiH2]
- Rubtsov, N. M., Azatyan, V. V., Tsvetkov, G. I., Temchin, S. M., "Detection of SiH2 from the A(1)B(1)-X(1)A(1) transition in the emission
spectrum of the rarified flame in the oxidation of silane", Mendeleev Communications, 187-188 (1997). [link to article][97RuAzTs.SiH2]
- Garcia-Cuesta, I., Sanchez-Marin, J., Sanchez de Meras, A., Ben Amor, N., "Assessment for the mean value total dressing method: Comparison with coupled cluster including triples methods for BF, NO+, CN+, C2, BeO, NH3, CH2, H2O, BH, HF, SiH2, Li2, LiNa, LiBe+, NeH+ and O3", Journal of Chemical Physics 107, 6306-6320 (1997). [link to article][97GaSaSa.O3]
- Matsunaga, N., Koseki, S., Gordon, M. S., "Relativistic potential energy surfaces of XH(2) (X=C, Si, Ge, Sn, and
Pb) molecules: Coupling of (1)A(1) and B-3(1) states", Journal of Chemical Physics 104, 7988-7996 (1996). [link to article][96MaKoGo.SiH2]
- Mineva, T., Russo, N., Sicilia, E., Toscano, M., "Spectroscopic constants of SiH2, GeH2, SnH2, and their cations and
anions from density-functional computations", International Journal of Quantum Chemistry 56, 669-675 (1995). [link to article][95MiRuSi.SiH2]
- Ishikawa, H., Kajimoto, O., "Reanalysis of the vibrational resonances of SiH2 in the (X)Over-Tilde
(1)A(1) state", Journal of Molecular Spectroscopy 174, 270-273 (1995). [link to article][95IsKaxx.SiH2]
- Jasinski, J. M., Becerra, R., Walsh, R., "Direct kinetic-studies of silicon hydride radicals in the gas-phase", Chemical Reviews 95, 1203-1228 (1995). [link to article][95JaBeWa.SiH2]
- Avery, L. W., Bell, M. B., Cunningham, C. T., Feldman, P. A., Hayward, R. H., Macleod, J. M., Matthews, H. E., Wade, J. D., "Submillimeter molecular line observations of IRC +10216: Searches for MgH, SiH2, and HCO(+), and detection of hot HCN", The Astrophysical Journal 426, 737-741 (1994). [link to article][94AvBeCu.MgH]
- Cramer, C. J., Dulles, F. J., Storer, J. W., Worthington, S. E., "Full valence complete active space SCF, multireference CI, and
density-functional calculations of 1A1-3B1 singlet-triplet gaps for the
valence-isoelectronic series BH2-, CH2, NH2+, AlH2-, SiH2, PH2+, GaH2-, GeH2, and AsH2+", Chemical Physics Letters 218, 387-394 (1994). [link to article][94CrDuSt.SiH2]
- Fukushima, M., Obi, K., "Rotational analysis of the SiD2 (A)Over-Tildeb-1(1)-(X)Over-Tilde(1)A(1)
transition observed in a Jet", Journal of Chemical Physics 100, 6221-6227 (1994). [link to article][94FuObxx.SiH2]
- Watts, J. D., Bartlett, R. J., "The inclusion of connected triple excitations in the Equation-of-Motion
Coupled-Cluster Mmethod", Journal of Chemical Physics 101, 3073-3078 (1994). [link to article][94WaBaxx.SiH2]
- Markus, M. W., Roth, P., "A quantitative ring dye-laser absorption diagnostic for free SiH2
((X)Over-Tilde(1)A(1)) radicals at high-temperatures", Journal of Quantitative Spectroscopy and Radiative Transfer 52, 783-789 (1994). [link to article][94MaRoxx.SiH2]
- Mick, H. J., Roth, P., Smirnov, V. N., Zaslonko, I. S., "Formation of hydrogen-atoms in silane pyrolysis behind shock-waves -
kinetics and thermochemistry of SiH4, SiH3, and SiH2 decomposition", Kinetics and Catalysis 35, 439-451 (1994).[94MiRoSm.SiH2]
- Gabriel, W., Rosmus, P., Yamashita, K., Morokuma, K., Palmieri, P., "Theoretical rotational vibrational-spectrum of SiH2 (X1A1 and A 3B1)", Chemical Physics 174, 45-56 (1993). [link to article][93GaRoYa.SiH2]
- Winter, C., Millie, P., "Theoretical study of small hydrogenated silicon compounds. I. Theoretical study of the SiH2 dissociation channels up to 8 eV excitation energy", Chemical Physics 174, 177-190 (1993). [link to article][93WiMix1.SiH]
- Winter, C., Millie, P., "Theoretical study of small hydrogenated silicon compounds. II. Role of the hybridization in SiHn (n=1, 2) as compared to CHn (n=1, 2)", Chemical Physics 174, 191-197 (1993). [link to article][93WiMixx.SiH]
- Duxbury, G., Alijah, A., Trieling, R. R., "Renner-Teller and spin-orbit interactions in SiH2", Journal of Chemical Physics 98, 811-825 (1993). [link to article][93DuAlTr.SiH2]
- Ishikawa, H., Kajimoto, O., "Vibrational analysis of SiH2 ((A)Tilde(1)B(1))", Journal of Molecular Spectroscopy 160, 1-10 (1993). [link to article][93IsKaxx.SiH2]
- Gabriel, W., Rosmus, P., "Selective mode excitations in the electronic ground-states of H2O, HDO, SiH2, and NH2", Journal of Physical Chemistry 97, 12644-12649 (1993). [link to article][93GaRoxx.SiH2]
- Fukushima, M., Mayama, S., Obi, K., "Jet spectroscopy and excited-state dynamics of SiH2 and SiD2", Journal of Chemical Physics 96, 44-52 (1992). [link to article][92FuMaOb.SiH2]
- Grev, R. S., Schaefer, H. F., "Thermochemistry of CHn, SiHn (n=0–4), and the cations SiH+, SiH2+, and SiH3+: A converged quantum mechanical approach", Journal of Chemical Physics 97, 8389-8406 (1992). [link to article][92GrScxx.SiH]
- McKay, R. I., Uichanco, A. S., Bradley, A. J., Holdsworth, J. R.
and Francisco, J. S., Steinfeld, J. I., Knight, A. E. W., "Direct observation of silicon (3P) following state-selected
photofragmentation of A 1B1 silylene", Journal of Chemical Physics 95, 1688-1695 (1991). [link to article][91McUiBr.SiH2]
- Ishikawa, H., Kajimoto, O., "Fermi resonance and vibrational analysis of SiH2 (A1A1) based on the LIF
excitation-spectra of the A1B1 (060)]-A1A1 (0-Upsilon''0) transitions", Journal of Molecular Spectroscopy 150, 610-619 (1991). [link to article][91IsKaxx.SiH2]
- Yamada, C., Kanamori, H., Hirota, E., Nishiwaki, N., Itabashi, N.
and Kato, K., Goto, T., "Detection of the silylene nu-2 band by infrared diode laser kinetic
spectroscopy", Journal of Chemical Physics 91, 4582-4586 (1989). [link to article][89YaKaHi.SiH2]
- Curtiss, L. A., Pople, J. A., "Theoretical enthalpies of formation of SiHn and SiHn+ (n = 1−4)", Chemical Physics Letters 144, 38-42 (1988). [link to article][88CuPoxx.SiH]
- Agrawal, P. M., Thompson, D. L., Raff, L. M., "Trajectory studies of unimolecular reactions of Si2H4 and SiH2 on a
global potential surface fitted to abinitio and experimental data", Journal of Chemical Physics 89, 741-750 (1988). [link to article][88AgThRa.SiH2]
- Francisco, J. S., Barnes, R., Thoman, J. W., "Dissociation dynamics of low-lying electronic states of SiH2", Journal of Chemical Physics 88, 2334-2341 (1988). [link to article][88FrBaTh.SiH2]
- Selmani, A., Salahub, D. R., "On the singlet triplet splitting in SiH2, GeH2, and SnH2. Local-spin-density
calculations", Journal of Chemical Physics 89, 1529-1532 (1988). [link to article][88SeSaxx.SiH2]
- Vanzoeren, C. M., Thoman, J. W., Steinfeld, J. I., Rainbird, M. W., "Production of Si(1D2) from electronically excited SiH2", Journal of Physical Chemistry 92, 9-11 (1988). [link to article][88VaThSt.SiH2]
- Nguyen, M. T., "Calculations on the electron-affinity of silylene (SiH2)", Journal of Molecular Structure: THEOCHEM 41, 391-397 (1988). [link to article][88Nguyen.SiH2]
- Kalcher, J., "Ab initio and pseudopotential investigations on the SiHn (n = 1–3) radicals and their anions", Chemical Physics 118, 273-284 (1987). [link to article][87Kalcher.SiH]
- Bauschlicher, C. W., Langhoff, S. R., Taylor, P. R., "On the 1A1-3B1 separation in CH2 and SiH2", Journal of Chemical Physics 87, 387-391 (1987). [link to article][87BaLaTa.SiH2]
- Bauschlicher, C. W., Taylor, P. R., "A full CI treatment of the 1A1, 1B1, and 3B1 states of SiH2", Journal of Chemical Physics 86, 1420-1424 (1987). [link to article][87BaTaxx.SiH2]
- Bauschlicher, C. W., Taylor, P. R., "Full CI benchmark calculations for several states of the same symmetry", Journal of Chemical Physics 86, 2844-2848 (1987). [link to article][87BaTaxxa.SiH2]
- Engel, Y. M., Levine, R. D., Thoman, J. W., Steinfeld, J. I., McKay, R. I., "Quantal fluctuations in fluorescence lifetimes of individual rovibronic
levels", Journal of Chemical Physics 86, 6561-6563 (1987). [link to article][87EnLeTh.SiH2]
- Thoman, J. W., Steinfeld, J. I., McKay, R. I., Knight, A. E. W., "Wide fluctuations in fluorescence lifetimes of individual rovibronic
levels in SiH2 (A1B1)", Journal of Chemical Physics 86, 5909-5917 (1987). [link to article][87ThStMc.SiH2]
- Koseki, S., Gordon, M. S., "Potential-energy surfaces and dynamic properties of three low-lying states
of silylene", Journal of Molecular Spectroscopy 123, 392-404 (1987). [link to article][87KoGoxx.SiH2]
- Bauschlicher, C. W., Taylor, P. R., "Full CI benchmark calculations for molecular-properties", Theoretica Chimica Acta 71, 263-276 (1987). [link to article][87BaTaxxb.SiH3]
- Allen, W. D., Schaefer, H. F., "Geometrical structures, force constants, and vibrational spectra of SiH, SiH2, SiH3, and SiH4", Chemical Physics 108, 243-274 (1986). [link to article][86AlScxx.SiH]
- Eley, C. D., Rowe, M. C. A., Walsh, R., "Relative rate studies for silylene", Chemical Physics Letters 126, 153-157 (1986). [link to article][86ElRoWa.SiH2]
- Gordon, M. S., Schmidt, M. W., "Potential triplet silylenes", Chemical Physics Letters 132, 294-298 (1986). [link to article][86GoScxx.SiH2]
- Obrien, J. J., Atkinson, G. H., "Detection of the SiH2 radical by intracavity laser-absorption
spectroscopy", Chemical Physics Letters 130, 321-329 (1986). [link to article][86ObAtxx.SiH2]
- Thoman, J. W., Steinfeld, J. I., "Laser-excited fluorescence detection of SiH2 produced in IR MPD of
organosilanes", Chemical Physics Letters 124, 35-38 (1986). [link to article][86ThStxx.SiH2]
- Balasubramanian, K., McLean, A. D., "The singlet triplet energy separation in silylene", Journal of Chemical Physics 85, 5117-5119 (1986). [link to article][86BaMcxx.SiH2]
- Noorbatcha, I., Raff, L. M., Thompson, D. L., Viswanathan, R., "Dynamics of unimolecular dissociation of silylene", Journal of Chemical Physics 84, 4341-4346 (1986). [link to article][86NoRaTh.SiH2]
- Shin, S. K., Beauchamp, J. L., "Proton affinity and heat of formation of silylene", Journal of Physical Chemistry 90, 1507-1509 (1986). [link to article][86ShBexx.SiH2]
- Gordon, M. S., "Potential-energy surfaces in singlet and triplet silylene", Chemical Physics Letters 114, 348-352 (1985). [link to article][85Gordon.SiH2]
- Fredin, L., Hauge, R. H., Kafafi, Z. H., Margrave, J. L., "Matrix-isolation studies of the reactions of silicon atoms with
molecular-hydrogen. The infrared-spectrum of silylene", Journal of Chemical Physics 82, 3542-3545 (1985). [link to article][85FrHaKa.SiH2]
- Viswanathan, R., Thompson, D. L., Raff, L. M., "A valence-bond potential-energy surface for silylene dissociation", Journal of Physical Chemistry 89, 1428-1432 (1985). [link to article][85ViThRa.SiH]
- Inoue, G., Suzuki, M., "Laser-induced fluorescence of the SiH2 radical", Chemical Physics Letters 105, 641-644 (1984). [link to article][84InSuxx.SiH2]
- Rice, J. E., Handy, N. C., "The low-lying states of silylene", Chemical Physics Letters 107, 365-374 (1984). [link to article][84RiHaxx.SiH2]
- Jasinski, J. M., Whittaker, E. A., Bjorklund, G. C., Dreyfus, R. W.
and Estes, R. D., Walkup, R. E., "Detection Oof SiH2 in silane and disilane glow-discharges by
frequency-modulation absorption-spectroscopy", Applied Physics Letters 44, 1155-1157 (1984). [link to article][84JaWhBj.SiH2]
- Colvin, M. E., Grev, R. S., Schaefer, H. F., Bicerano, J., "X1A1, A3B1, and A1B1 electronic states of silylenes. Structures and
vibrational frequencies of SiH2, SiHF, and SIF2", Chemical Physics Letters 99, 399-405 (1983). [link to article][83CoGrSc.SiH2]
- Okeefe, J. F., Lampe, F. W., "Spectroscopic detection of silylene in the infrared multiphoton
decomposition of silane", Applied Physics Letters 42, 217-219 (1983). [link to article][83OkLaxx.SiH2]
- Ball, J. R., Thomson, C., "Electronic-structure of SiH2, PH2, and their positive and negative-ions", International Journal of Quantum Chemistry 14, 39-53 (1978). [link to article][78BaThxx.SiH2]
- Heaton, M. M., "Theoretical studies of electron-affinity of SiH2", Journal of Chemical Physics 67, 5396-5398 (1977). [link to article][77Heaton.SiH2]
- Meadows, J. H., Schaefer, H. F., "One-configuration and 2-configuration Hartree-Fock limit pedictions for
singlet-triplet separation in methylene and silylene", Journal of the American Chemical Society 98, 4383-4386 (1976). [link to article][76MeScxx.SiH2]
- Dubois, I., Duxbury, G., Dixon, R. N., "Renner effect in SiH2", Journal of the Chemical Society, Faraday Transactions 71, 799-806 (1975). [link to article][75DuDuDi.SiH2]
- Leibovici, C., Labarre, J. F., "Quantum approach of ground-state of silylene radical - Singlet or
triplet", Journal de chimie physique et de physico-chimie biologique 72, 951-952 (1975). [link to article][75LeLaxx.SiH2]
- Zeck, O. F., Su, Y. Y., Gennaro, G. P., Tang, Y. N., "Ground electronic state of silylene", Journal of the American Chemical Society 96, 5967-5973 (1974). [link to article][74ZeSuGe.SiH2]
- Higuchi, J., Kubota, S., Kumamoto, T., Tokue, I., "Contribution of D orbitals in SiH SiH2, SiH3, and SiH4", Bulletin of the Chemical Society of Japan 47, 2775-2780 (1974). [link to article][74HiKuKu.SiH2]
- Wirsam, B., "Ab-initio potential curves for radical SiH2", Chemical Physics Letters 14, 214-216 (1972). [link to article][72Wirsam.SiH2]
- Dubois, I., "Absorption spectrum of free SiH2 radical", Canadian Journal of Physics 46, 2485-2490 (1968). [link to article][68Dubois.SiH2]
- Dubois, I., Herzberg, G., Verma, R. D., "Spectrum of SiH2", Journal of Chemical Physics 47, 4262 (1967). [link to article][67DuHeVe.SiH2]
- Jordan, P. C., "Lower electronic levels of radicals SiH SIH2 and SiH30", Journal of Chemical Physics 44, 3400 (1966). [link to article][66Jordan.SiH2]
The ExoMol bibliometrician is Olga Yurchenko